2-[2-(Methyl­amino)­benzo­yl]-2,3,4,9-tetra­hydro-1H-pyrido[3,4-b]indol-1-one

نویسندگان

  • Lin Li
  • Yu-Tao Zhang
چکیده

The title compound, C(19)H(17)N(3)O(2), was obtained from fruits of Evodia Rutaecarpa. In the solid state, the dihedral angle between the 2,3,4,9-tetra-hydro-1H-pyrido[3,4-b]indol-1-one (tetra-hydro-β-carbolinone) unit and the benzoyl ring is 61.46 (3)°. In the crystal, dimers are formed through inter-molecular N-H⋯O hydrogen-bonding inter-actions. In addition, intra-molecular N-H⋯O hydrogen bonds are also observed. C-H⋯π contacts connect the dimers, leading to the formation of a three-dimensional supra-molecular network.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A New Diketopiperazine from the Marine Sponge Callyspongia Species

Chemical investigation of the sponge Callyspongia sp. from the South China Sea afforded one new diketopiperazine, cyclo-(R-Pro-6-hydroxyl-S-Ile) (1), along with six known diketopiperazines: staphyloamide A (2), cyclo(S-Pro-S-Phe) (3), cyclo-(R-Pro-R-Phe) (4), cyclo-(S-Pro-R-Leu) (5), cyclo-(S-Pro-R-Ala) (6), cyclo(R-Tyr-R-Phe) (7), and three known tryptophan-derived alkaloids: C 2 -α-D-mannosyl...

متن کامل

Further exploration of the heterocyclic diversity accessible from the allylation chemistry of indigo

Diversity-directed synthesis based on the cascade allylation chemistry of indigo, with its embedded 2,2'-diindolic core, has resulted in rapid access to new examples of the hydroxy-8a,13-dihydroazepino[1,2-a:3,4-b']diindol-14(8H)-one skeleton in up to 51% yield. Additionally a derivative of the novel bridged heterocycle 7,8-dihydro-6H-6,8a-epoxyazepino[1,2-a:3,4-b']diindol-14(13H)-one was produ...

متن کامل

6-Bromo-2-(3-phenyl­allyl­idene)-2,3,4,9-tetra­hydro-1H-carbazol-1-one

Mol-ecules of the title compound, C(21)H(16)BrNO, are linked through pairs of N-H⋯O inter-molecular hydrogen bonds into centrosymmetric R(2) (2)(10) dimers. One of the C atoms of the cyclohex-2-enone ring is disordered with refined occupancies of 0.61 (2) and 0.39 (2).

متن کامل

A facile synthesis of 3-substituted 9H-pyrido[3,4-b]indol-1(2H)-one derivatives from 3-substituted beta-carbolines.

A mild and efficient two-step synthesis of 3-substituted beta-carbolinone derivatives from 3-substituted beta-carboline in good yields is described. A possible reaction mechanism for the formation of the skeleton of beta-carbolin-1-one is proposed. The structures of these compounds were established by IR, 1H-NMR, 13C-NMR, mass spectrometry and elemental analysis, as well as X-ray crystallograph...

متن کامل

(E)-6-Chloro-2-(furan-2-yl­methyl­idene)-2,3,4,9-tetra­hydro-1H-carbazol-1-one

In the title compound, C(17)H(12)ClNO(2), the carbazole unit is nearly planar [maximum deviation = 0.052 (1) Å]. The pyrrole ring makes dihedral angles of 1.92 (8) and 4.71 (11)° with the benzene and furan rings, respectively. Inter-molecular N-H⋯O hydrogen bonds form R(2) (2)(10) rings in the crystal structure.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010